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A categorical listing of Spider-Man's Arch-Villains curated by Key Collector Comics.
- 3rd appearance of Spider-Man
- 1st appearance of Vulture
- 1st appearance of the Terrible Tinkerer
- 1st appearance of Quentin Beck (becomes Mysterio) disguised as the Terrible Tinkerer's alien assistant
- 1st appearance of Kraven the Hunter
- 2nd appearance of the Chameleon
- 1st time Mary Jane Watson is mentioned, after Aunt May arranged a date for her and Peter
- *a trusted source has told Key Collector Comics that Kraven has been cast for an upcoming solo film (July 5, 2019)
- 1st appearance of Man-Wolf. the son of J Jonah Jameson, John was an astronaut who discovered an amulet that turned him into a werewolf
- *Agent Stroud (to be played by Tyrese Gibson in Morbius) hunted Man-Wolf in the comics